XAFS Journal Club

The conservation of marine archaeological wood is complicated by the presence of iron and sulfur. The sulfur originates from sulfate ions in seawater being transformed by sulfur reducing bacteria, and iron from dissolved fixture and artefacts. Incorporated in to the wood as reduced sulfur/iron compounds, such as pyrite, they can become problematic during the drying […]

Using High-Energy-Resolution-Fluorescence-Detection (HERFD), one can sharpen the pre-edge structures revealing their multiplet nature. In ionic systems, they can be calculated from the transition from the 3dN ground state to the 1s13dN+1 final state, where covalent systems need the inclusion of charge transfer effects. The main edge is usually interpreted from the calculation of the transitions […]

We will look at how electrochemically active materials such as batteries can be studied in a concerted way by tuning to relevant resonant x-ray absorption at both the soft and the hard x-ray energy regimes. We will specifically examine the role of oxygen in the charge compensation of LiMO2 delafossite compounds, that serve as cathodes […]

I will present details of the TES Beamline at the National Synchrotron Light Source II, covering its design, commissioning, and early results. Its scientific mission includes static and in-situ/operando XRF imaging and spatially resolved (microbeam) XAS -- in the tender energy range -- for characterization of complex heterogeneous, structured and dynamic natural or engineered materials […]

Modern electronic structure theory and computational methods now permit efficient calculations of ground state properties, as exemplified by the tabulation of many-thousands of structures in the Materials Project . Complementary advances in the theory of excited states have led to efficient methods for calculations of x-ray and electron spectroscopies, e.g., using the real-space Green's multiple […]

The presentation will be a collection of thoughts that I find interesting for the experimentalist employing hard X-ray photon-in/photon-out spectroscopy with a wavelength dispersive instrument. I would like to draw the attention to some experimental aspects and will give hopefully useful advice that may be considered for the experimental protocol. Furthermore, I will present the […]

The new painting materials used by the Impressionists, Fauvists, and Expressionists were critical components of their break with traditional modes of representation. These artists heavily exploited the synthetic organic and inorganic pigments that were newly available as a result of the industrial revolution. However, the bright and novel hues that made their way onto these […]

Presented will be a discussion of efforts to employ a wavelet transform (WT) analysis towards the quantitative structural determination of discrete molecular systems using an EXAFS analysis. Unlike a transition Fourier transform (FT) analysis, a WT analysis yields a 2D plot in both k- and R-space. Thus, information contained in k-space that can be lost […]