XAFS Journal Club
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Jerry Seidler: What is X-ray Raman Scattering, and What Did Raman Have to Do With It?
Jerry Seidler: What is X-ray Raman Scattering, and What Did Raman Have to Do With It?
X-ray Raman Scattering (XRS, often also called nonresonant inelastic x-ray scattering), is a hard x-ray alternative to soft x-ray NEXAFS. I'll review the basic physics, including the role of momentum transfer to tune selection rules. And I'll explain Raman's involvement, or lack thereof. References: https://journals.aps.org/prb/abstract/10.1103/PhysRevB.74.214117 and https://journals.aps.org/prl/abstract/10.1103/PhysRevLett.105.053202 https://www.youtube.com/watch?v=kuKA81-R7-w
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Simo Huotari: X-ray Raman spectroscopy: glimpse of the state of the art for samples in complex environments
Simo Huotari: X-ray Raman spectroscopy: glimpse of the state of the art for samples in complex environments
In this lecture I will continue where the previous lecture ends and talk about some examples of how XRS is used to study materials under high pressure and chemical reactions. References: https://www.nature.com/articles/nmat3031 and https://pubs.acs.org/doi/abs/10.1021/jp912208v https://www.youtube.com/watch?v=mGD3HqwaitU&t=1205s
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Evan Jahrman Core-to-core X-ray Emission Spectroscopy: Pitfalls and Advantages for Lab-based and Synchrotron Users
Evan Jahrman Core-to-core X-ray Emission Spectroscopy: Pitfalls and Advantages for Lab-based and Synchrotron Users
Core-to-core X-ray emission spectroscopy (CTC-XES) has not only provided key insights into atomic physics but is extremely well positioned to serve as a major analytical technique for several materials systems in the coming decades. Moreover, CTC-XES frequently serves as an enabling phenomenon for more exotic varieties of synchrotron-based XAFS. I will cover several applications of […]
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Adam Hitchcock: Soft X-ray Spectromicroscopy in Scanning Transmission X-ray Microscopes
Adam Hitchcock: Soft X-ray Spectromicroscopy in Scanning Transmission X-ray Microscopes
Soft X-ray scanning transmission microscopy (STXM) is a powerful tool for nanoscale materials analysis, with significant advantages over analytical electron microscopies for studies of radiation sensitive materials. Chemical species identified by near edge X-ray absorption fine structure (NEXAFS) spectra can be mapped quantitatively in 2D and in 3D. STXM instrumentation and methods will be described, […]
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Kelsey Morgan: Hot science with cool sensors
Kelsey Morgan: Hot science with cool sensors
The transition-edge sensor (TES) microcalorimeter uses the sharply temperature-dependent resistance of the superconducting transition to measure the energy of X-ray and gamma ray photons. A single TES is a broadband, energy-dispersive area detector capable of eV-scale energy resolution with good quantum efficiency. With an array of hundreds or thousands of sensors, a TES-based spectrometer can […]
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Martin McBriarty: Top-Down Approaches to EXAFS Analysis
Martin McBriarty: Top-Down Approaches to EXAFS Analysis
EXAFS spectra are often modeled using a small number of virtual coordination shells which can vary in coordination number, bond length, and disorder. While this bottom-up approach is generally successful for single-phase samples, it becomes intractable when the element of interest occupies multiple complex coordination states. Such cases may require a top-down approach, in which […]